Location: Plant Polymer Research
Title: Structure-function properties of starch graft poly(methyl acrylate)copolymers Author
Submitted to: Meeting Abstract
Publication Type: Abstract Only
Publication Acceptance Date: January 15, 2014
Publication Date: May 16, 2014
Citation: Finkenstadt, V.L. 2014. Structure-function properties of starch graft poly(methyl acrylate)copolymers. Meeting Abstract. Technical Abstract: Spherulites, produced by steam jet-cooking high-amylose starch and oleic acid, were grafted with methyl acrylate, both before and after removal of un-complexed amylopectin. For comparison, granular high-amylose corn starch was graft polymerized in a similar manner. The amount of grafted and ungrafted poly(methyl acrylate) were similar for all starch-graft-poly(methyl acrylate) copolymers. Ribbons were extruded, and tensile properties were determined. Although extruded ribbons with similar tensile strength were obtained from the three starch-PMA graft copolymers, much higher values for elongation were obtained from the spherulite-containing copolymers. The graft frequency and molecular weights of grafted poly(methyl acrylate) showed an interesting correlation to the tensile elongation of the extruded sample.