Scientific Technology Transfer Coordinator
(309) 273–4298
Dr. Kenneth Doll serves the scientists of the Midwest Area utilizing the large variety of technology transfer options that are available in ARS. These include Cooperative Research and Development Agreements (CRADAs), Material Transfer Agreements (MTAs) and Data Transfer Research Agreements (DTRAs). Dr. Doll helps connect the area scientists with companies, universities, and other research organizations. Dr. Doll also helps coordinate the interactions of area scientists with ARS patent advisors and facilitates the submission of internal ARS proposal. Finally, Dr. Doll serves in the training of Midwest Area scientists regarding technology transfer issues.
Muturi, E.J., Doll, K.M., Dunlap, C.A. 2023. Non-target effects of essential oils on selected beneficial bacteria. Journal of Plant Diseases and Protection. https://doi.org/10.1007/s41348-023-00825-6.
Evangelista, R.L., Dexter, N.I., Liu, S., Ulmasov, T., Doll, K.M., Cermak, S.C. 2023. Utilizing native myrosinase in pennycress (Thlaspi arvense) seeds to reduce glucosinolates in the defatted meal [abstract]. American Oil Chemists' Society (AOCS) Annual Meeting & Expo, 4/30/23-5/3/23, Denver, CO.
Doll, K.M., Moser, B.R. 2023. Industrial chemicals via decarboxylation of natural carboxylic acids. In: Liu, Z., Kraus, G., editors. Green Chemistry and Green Materials from Plant Oils and Natural Acids. Vol. 83. Cambridge, UK:Royal Society of Chemistry Publishing. p. 144-158. https://doi.org/10.1039/9781837671595.
Moser, B.R., Dorado, C., Bantchev, G.B., Winkler-Moser, J.K., Doll, K.M. 2023. Production and evaluation of biodiesel from sweet orange (Citrus sinensis) lipids extracted from waste seeds from the commercial orange juicing process. Fuel. 342. Article 127727. https://doi.org/10.1016/j.fuel.2023.127727.
Moser, B.R., Doll, K.M., Cermak, S.C. 2023. Biopolymers synthesized from ring opening polymerization of epoxidized vegetable oils with multifunctional renewable acids [abstract]. American Chemical Society Spring 2023 Meeting & Exposition. Paper ID 3811062.
Bantchev, G.B., Doll, K.M. 2022. Comparative amine-catalyzed thia-Michael reactions of primary and secondary thiols with maleic and itaconic anhydrides and esters. ChemistrySelect. 7(48). Article e202204138. https://doi.org/10.1002/slct.202204138.
Doll, K.M., Muturi, E.J., Flor-Weiler, L.B. 2022. Combining TEMPO and methyl undecenoate to produce an effective anti-mosquito compound with convenient spin-labeling. Experimental Parasitology. 244. Article 108440. https://doi.org/10.1016/j.exppara.2022.108440.
Moser, B.R., Doll, K.M., Price, N.P. 2022. Comparison of aliphatic polyesters prepared by acyclic diene metathesis and thiol-ene polymerization of alpha,omega-polyenes arising from oleic acid-based 9-decen-1-ol. Journal of the American Oil Chemists' Society. 100:149-162. https://doi.org/10.1002/aocs.12668
Doll, K.M., Cermak, S.C. 2022. Selective electrochemical oxidation of alcohols catalyzed by partially biobased TEMPO analogs. ChemistrySelect. 7(29). Article e202201736. https://doi.org/10.1002/slct.202201736.
Moser, B.R., Cermak, S.C., Doll, K.M., Kenar, J.A., Sharma, B.K. 2022. A review of fatty epoxide ring opening reactions: Chemistry, recent advances, and applications. Journal of the American Oil Chemists' Society. 99(10):801-842. https://doi.org/10.1002/aocs.12623.
Moser, B.R., Jackson, M.A., Doll, K.M. 2022. Serendipitous production of industrially useful p-cymene by catalytic dehydration and isomerization of perillyl alcohol [abstract]. American Oil Chemists' Society Annual Meeting and Expo. p. 10.
Hay, W.T., Anderson, J.A., McCormick, S.P., Hojilla-Evangelista, M.P., Selling, G.W., Utt, K.D., Bowman, M.J., Doll, K.M., Ascherl, K.L., Berhow, M.A., Vaughan, M.M. 2022. Fusarium head blight resistance exacerbates nutritional loss of wheat grain at elevated CO2. Scientific Reports. 12. Article 15. https://doi.org/10.1038/s41598-021-03890-9.
Doll, K.M., Moser, B.R., Knothe, G. 2021. Decarboxylation of oleic acid using iridium catalysis to form products of increased aromatic content compared to ruthenium systems. International Journal of Sustainable Engineering. 14(6):2018-2024. https://doi.org/10.1080/19397038.2021.1978589.
Doll, K.M., Moser, B.R. 2001. Comparison of iridium-, ruthenium-, and osmium-catalyzed decarboxlyation catalysts of 9-cis-octadecenoic acid relevant to biobased fuel production [abstract]. American Chemical Society National Meeting, August 22-26, 2021, Atlanta, GA. Abstract #3085081.
Moser, B.R., Banks, B.N., Doll, K.M. 2021. Synthesis and properties of renewable, aliphatic polyesters from thiol-ene and acyclic diene metathesis polymerization of alpha, omega-unsaturated dienes derived from fatty acids [abstract]. VIRTUAL 2021 American Oil Chemists' Society Annual Meeting and Expo.
Moser, B.R., Jackson, M.A., Doll, K.M. 2021. Production of industrially useful and renewable p-cymene by catalytic dehydration and isomerization of perillyl alcohol. Journal of the American Oil Chemists' Society. 98(3):305–316. https://doi.org/10.1002/aocs.12468.
Hwang, H., Ball, J.C., Doll, K.M., Vermillion, K. 2020. Analysis of polymers formed during frying french fries in soybean oil. Meeting Abstract. IFT Annual Meeting & Food Expo 2020. July 12-15, 2020, Chicago, IL.
Muturi, E.J., Hay, W.T., Doll, K.M., Ramirez, J.L., Selling, G.W. 2020. Insecticidal activity of Commiphora erythraea essential oil and its emulsions against larvae of three mosquito species. Journal of Medical Entomology. 57(6):1835-1842. https://doi.org/10.1093/jme/tjaa097.
Hwang, H.-S., Ball, J.C., Doll, K.M., Anderson, J.E., Vermillion, K. 2020. Investigation of polymers and alcohols produced in oxidized soybean oil at frying temperatures. Food Chemistry. 317:126379. https://doi.org/10.1016/j.foodchem.2020.126379.
Muturi, E.J., Selling, G.W., Doll, K.M., Hay, W.T., Ramirez, J.L. 2020. Leptospermum scoparium essential oil is a promising source of mosquito larvicide and its toxicity is enhanced by a biobased emulsifier. PLoS One. 15(2):e0229076. https://doi.org/10.1371/journal.pone.0229076.
Moser, B.R., Vermillion, K.E., Banks, B.N., Doll, K.M. 2020. Renewable aliphatic polyesters from fatty dienes by acyclic diene metathesis polycondensation. Journal of the American Oil Chemists' Society. 97(5):517-530. https://doi.org/10.1002/aocs.12338.
Doll, K.M. 2019. Using biobased materials to modify vinyl alcohol based polymers [abstract]. Society of Tribologists and Lubrication Engineers local section meeting, November 6, 2019, Peoria, IL, Zoom Virtual Meeting.
Liu, S.X., Hwang, H., Moser, J.K., Doll, K.M. 2019. Antioxidative effect of amino acids on frying [abstract]. Euro Fed Lipid Congress and Expo, Seville, Spain, October 20-23, 2019.
Doll, K.M. 2019. A route to biobased polymers and organogels without transvinylation [abstract]. Gordon Research Conference on Biomass to Biobased Chemicals and Materials, July 14-19, 2019, Newry, ME.
Hwang, H.-S., Winkler-Moser, J.K., Doll, K.M., Gadgil, M., Liu, S.X. 2019. Factors affecting antioxidant activity of amino acids in soybean oil at frying temperatures. European Journal of Lipid Science and Technology. https://doi.org/10.1002/ejlt.201900091.
Moser, B.R., Doll, K.M., Peterson, S.C. 2019. Renewable poly(thioether-ester)s from fatty acid derivatives via thiol-ene photopolymerization. Journal of the American Oil Chemists' Society. 96(7):825-837. https://doi.org/10.1002/aocs.12244.
Muturi, E.J., Doll, K.M., Berhow, M.A., Weiler, L., Rooney, A.P. 2019. Honeysuckle essential oil as a potential source of ecofriendly larvicides for mosquito control. Pest Management Science. 75(7):2043-2048. https://doi.org/10.1002/ps.5327.
Muturi, E.J., Doll, K.M., Ramirez, J.L., Rooney, A.P. 2018. Bioactivity of wild carrot (Daucus carota, Apiaceae) essential oil against mosquito larvae. Journal of Medical Entomology. https://doi.org/10.1093/jme/tjy226.
Hwang, H., Moser, J.K., Doll, K.M., Gadgil, M., Liu, S.X. 2019. Practical application of amino acids as natural antioxidants for frying [abstract]. American Oil Chemists' Society Annual Meeting & Expo. Paper No. 4B-1025.
Doll, K.M., Dunn, R.O., Ascherl, K.L., Bantchev, G.B. 2019. Vegetable oil-based removal of harmful metals from water. Inform. 30(2):14-18.
Dunn, R.O., Bantchev, G.B., Doll, K.M., Ascherl, K.L., Lansing, J.C., Murray, R.E. 2018. Thioether-functionalized corn oil biosorbents for the removal of mercury and silver ions from aqueous solutions. Journal of the American Oil Chemists' Society. 95:1189-1200. https://onlinelibrary.wiley.com/doi/abs/10.1002/aocs.12089.
Doll, K.M., Walter, E.L., Murray, R.E., Hwang, H.-S. 2018. Organogel polymers from 10-undecenoic acid and poly(vinyl acetate). Journal of Polymers and the Environment. 26:3670-3676. https://doi.org/10.1007/s10924-018-1241-4.
Knothe, G., Steidley, K.R., Moser, B.R., Doll, K.M. 2017. Decarboxylation of fatty acids with triruthenium dodecacarbonyl: Influence of the compound structure and analysis of the product mixtures. ACS Omega. 2:6473-6480.
Muturi, E.J., Ramirez, J.L., Doll, K.M., Bowman, M.J. 2017. Combined toxicity of three essential oils against Aedes aegypti (Diptera: Culicidae) larvae. Journal of Medical Entomology. 54:1684-1691. doi: 10.1093/jme/tjx168.
Doll, K.M., Walter, E.L., Murray, R.E. 2018. Decarboxylation of cinnamic acids using a ruthenium sawhorse. International Journal of Sustainable Engineering. 11(1):26-31.
Doll, K.M., Bantchev, G., Murray, R.E. 2017. Using ruthenium sawhorse based decarboxylation to produce industrial materials from oleic acid [abstract]. American Chemical Society Great Lakes Regional Meeting, Organic Chemistry section, GLRM 49, June 27-30, 2017, Fargo, ND. p. 5.
Doll, K.M., Cermak, S.C., Kenar, J.A., Walter, E.L., Isbell, T.A. 2017. Derivatization of castor oil based estolide esters: Preparation of epoxides and cyclic carbonates. Industrial Crops and Products. 104:269-277.
Doll, K.M., Bantchev, G.B., Walter, E.L., Murray, R.E., Appell, M., Lansing, J.C., Moser, B.R. 2017. Parameters governing ruthenium sawhorse-based decarboxylation of oleic acid. Industrial and Engineering Chemistry Research. 56(4):864-871.
Moser, B.R., Knothe, G., Walter, E.L., Murray, R.E., Dunn, R.O., Doll, K.M. 2016. Analysis and properties of the decarboxylation products of oleic acid by catalytic triruthenium dodecacarbonyl. Energy and Fuels. 30(9):7443-7451.
Doll, K.M., Cermak, S.C., Kenar, J.A., Isbell, T.A., 2016. Synthesis and characterization of estolide esters containing epoxy and cyclic carbonate groups. Journal of the American Oil Chemists' Society. 93(8):1149-1155.
Kenar, J.A., Cermak, S.C., Doll, K.M., Isbell, T. 2016. Synthesis and characterization of estolides containing epoxy and cyclic carbonate groups [abstract]. American Oil Chemists' Society.
Chandrasekaran, S.R., Murali, D., Marley, K.A., Larson, R.A., Doll, K.M., Moser, B.R., Scott, J., Sharma, B.K. 2016. Antioxidants from slow pyrolysis bio-oil of birch wood: Application for biodiesel and biobased lubricants. ACS Sustainable Chemistry & Engineering. 4:1414-1421.
Doll, K.M., Walter, E.L., Bantchev, G.B., Jackson, M.A., Murray, R.E., Rich, J.O. 2016. Improvement of lubricant materials using ruthenium isomerization. Chemical Engineering Communications. 203(7):901-907.
Bantchev, G.B., Doll, K.M., Biresaw, G., Vermillion, K. 2015. Sulfuric acid as a catalyst for ring-opening of biobased bis-epoxides. Pacifichem Symposium. ENRG 292.
Murray, R.E., Bantchev, G.B., Dunn, R.O., Ascherl, K.L., Doll, K.M. 2015. Biobased thioethers as metal-absorbing ligands [abstract]. Pacifichem 2015 - The International Chemical Congress of Pacific Basin Societies, December 15-20, 2015, Honolulu, HI. ORGN 2148.
Knothe, G.H., Doll, K.M., Moser, B.R., Murray, R.E. 2015. Three approaches to fuels from fatty compounds [abstract]. Annual Meeting and Expo of the American Oil Chemists' Society.
Doll, K.M., Moser, B.R., Liu, Z., Murray, R.E. 2016. Producing monomers and polymers from plant oils. In: Sharma, B.K., Biresaw, G., editors. Environmentally Friendly and Biobased Lubricants. Boca Raton: CRC Press. p. 79-98.
Moser, B.R., Murray, R.E., Doll, K.M. 2015. Fuel properties of heptadecene isomers prepared via tandem isomerization-decarboxylation of oleic acid [abstract]. Proceedings of American Chemical Society National Meeting, Energy and Fuels Division, ENFL 323, p. 148.
Murray, R.E., Walter, E.L., Doll, K.M. 2015. Tandem isomerization-decarboxylation of unsaturated fatty acids to olefins via ruthenium metal-as-ligand catalysts [abstract]. American Chemical Society National Meeting, Catalysis Science and Technology Division, CATL 239. p. 97.
Bantchev, G.B., Doll, K.M., Biresaw, G., Vermillion, K. 2015. Formation of furan fatty alkyl esters from their bis-epoxide fatty esters [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting & Exhibition. p. 38.
Moser, B.R., Doll, K.M., Murray, R.E., Knothe, G.H. 2015. Fuel properties of heptadecene isomers prepared via tandem isomerization-decarboxylation of oleic acid [abstract]. Annual Meeting and Expo of the American Oil Chemists' Society. Abstract No. 61704.
Bantchev, G.B., Doll, K.M., Biresaw, G., Vermillion, K. 2015. Formation of furan fatty alkyl esters from their bis-epoxide fatty esters [abstract]. Annual Meeting and Expo of the American Oil Chemists' Society. Abstract No. 61580.
Bantchev, G.B., Doll, K.M., Biresaw, G., Vermillion, K. 2014. Formation of furan fatty alkyl esters from their bis-epoxide fatty esters. Journal of the American Oil Chemists' Society. 91:2117-2123.
Biresaw, G., Sharma, B.K., Bantchev, G.B., Kurth, T.L., Doll, K.M., Erhan, S.Z., Kunwar, B., Scott, J.W. 2014. Elastohydrodynamic properties of biobased heat-bodied oils. Industrial and Engineering Chemistry Research. 53:16183-16195.
Murray, R.E., Walter, E.L., Doll, K.M. 2014. Tandem isomerization-decarboxylation for converting alkenoic fatty acids into alkenes. American Chemical Society (ACS) Catalysis. 4:3517-3520.
Murray, R.E., Walter, E.L., Doll, K.M. 2014. Bio-olefins from unsaturated fatty acids via tandem catalysis [abstract]. Asia-Pacific Resilience Innovation Summit and Expo, 9/15/14-9/17/14, Honolulu, HI. www.islandsconnect.com/program. Poster 108.
Sharma, B.K., Scott, J., Murali, D., Larson, R.A., Marley, K.A., Doll, K.M., Moser, B.R., Rajagopalan, N. 2014. Chemicals derived from pyrolysis bio-oils as antioxidants in fuels and lubricants [abstract]. Thermocatalytic Conference (TCS) 2014, Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products, September 2-5, 2014, Denver, CO. p. 29.
Doll, K.M. 2015. Chemical synthesis of carbonates, esters, and acetals from soybean oil. In: Liu, Z., Kraus, G., editors. Green Materials from Plant Oils. 1st edition. Cambridge, UK: RSC Publishing. p. 28-40.
Sharma, B.K., Doll, K.M., Marley, K.A., Murali, D., Larson, R.A. 2014. Pyrolysis bio-oils as additives for vegetable oil based lubricants [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting & Exhibition. p. 59.
Sharma, B.K., Moser, B.R., Vermillion, K., Doll, K.M., Rajagopalan, N. 2014. Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags. Fuel Processing Technology. 122:79-90.
Biresaw, G., Sharma, B.K., Bantchev, G.B., Kurth, T.L., Doll, K.M., Erhan, S.Z. 2014. Elastohydrodynamic properties of heat-bodied oils [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting and Exhibition. p. 43.
Doll, K.M. 2014. Increased functionality of methyl oleate using alkene metathesis. International Journal of Sustainable Engineering. 7(4):322-329.
Hwang, H., Doll, K.M., Moser, J.K., Vermillion, K., Liu, S.X. 2013. Is it true that polymerization of vegetable oil occurs through Diels-Alder reaction? [abstract]. American Chemical Society.
Murray, R.E., Bantchev, G.B., Dunn, R.O., Ascherl, K.L., Doll, K.M. 2013. Heavy metal absorbing Thioether-functionalized ligands derived from vegetable oils [abstract]. American Chemical Society National Meeting & Exposition, September 8-12, 2013, Indianapolis, IN.
Murray, R.E., Bantchev, G.B., Dunn, R.O., Ascherl, K.L., Doll, K.M. 2013. Thioether-functionalized vegetable oils: Metal-absorbing biobased ligands. ACS Sustainable Chemistry & Engineering. 1:562-565.
Doll, K.M., Hwang, H. 2013. Thermal modification of vegetable oils. Lipid Technology. 25(4):83-85.
Hwang, H.-S., Doll, K.M., Winkler-Moser, J.K., Vermillion, K., Liu, S.X. 2013. No evidence found for Diels-Alder reaction products in soybean oil oxidized at the frying temperature by NMR study. Journal of the American Oil Chemists' Society. 90(6):825-834.
Doll, K.M., Sharma, B.K., Myslinska, M., Heise, G.L. 2013. Boron brings big benefits to bio-based blends [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting & Expo. p. 68.
Doll, K.M., Bantchev, G.B., Murray, R.E. 2013. Bismuth(III) trifluoromethanesulfonate catalyzed ring opening reaction of mono epoxy oleochemicals to form keto and diketo derivatives. ACS Sustainable Chemistry & Engineering. 1:39-45.
Erhan, S.Z., Sharma, B.K., Doll, K.M. 2012. Improving vegetable oil properties for lubrication methods. Machinery Lubrication. Article 28510. p. 1-2.
Arca, M., Sharma, B.K., Perez, J.M., Doll, K.M. 2013. Gear oil formulation designed to meet bio-preferred criteria as well as give high performance. International Journal of Sustainable Engineering. 6(4):326-331.
Sharma, B.K., Doll, K.M., Heise, G.L., Myslinska, M., Erhan, S.Z. 2012. Anti-wear additive derived from soybean oil and boron utilized in a gear oil formulation. Industrial and Engineering Chemistry Research. 51:11941-11945.
Doll, K.M., Sharma, B.K., Heise, G.L., Myslinska, M. 2012. Formulation of a biobased gear oil utilizing boron technology [abstract]. International Joint Tribology Conference. p. 41.
Chintareddy, V.R., Oshel, R.E., Doll, K.M., Yu, Z., Wu, W., Zhang, G., Verkade, J.G. 2012. Investigation of conjugated soybean oil as drying oils and CLA sources. Journal of the American Oil Chemists' Society. 89:1749-1762.
Selling, G.W., Hojillaevangelist, M.P., Evangelista, R.L., Isbell, T., Price, N.P., Doll, K.M. 2013. Extraction of proteins from pennycress seeds and press cake. Industrial Crops and Products. 41(1):113-119.
Doll, K.M., Biswas, A. 2013. A biobased nitrogen-containing lubricant additive synthesized from expoxidized methyl oleate using an ionic liquid catalyst. In: Biresaw, G., Mittal, K.L., editors. Surfactants in Tribology. Volume 3. Boca Raton, FL: CRC Press. p. 131-145.
Arca, M., Sharma, B.K., Perez, J.M., Doll, K.M. 2012. Isothermal thermogravimetric analysis of soybean oil oxidation correlated to thin film micro-oxidation test methods. Industrial and Engineering Chemistry Research. 51:3550-3555.
Sharma, B.K., Shah, S.N., Doll, K.M., Erhan, S.Z. 2012. Screening of natural oil basestocks for lubricant applications [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting & Expo. p. 60.
Hughes, S.R., Moser, B.R., Robinson, S., Cox, E.J., Harmsen, A.J., Friesen, J.A., Bischoff, K.M., Jones, M.A., Pinkleman, R., Bang, S.S., Tasaki, K., Doll, K.M., Qureshi, N., Liu, S., Saha, B.C., Jackson, Jr., J.S., Cotta, M.A., Rich, J.O., Caimi, P. 2012. Synthetic resin-bound truncated Candida antarctica lipase B for production of fatty acid alkyl esters by transesterification of corn and soybean oils with ethanol or butanol. Journal of Biotechnology. 159:69-77. DOI: 10.1016/j.jbiotec.2012.01.025.
Doll, K.M., Vermillion, K., Fanta, G.F., Liu, Z. 2012. Diffusion coefficients of water in biobased hydrogel polymer matrices by NMR imaging. Journal of Applied Polymer Science. 125:E580-E585.
Arca, M., Sharma, B.K., Price, N.P.J., Perez, J.M., Doll, K.M. 2012. Evidence contrary to the accepted Diels-Alder mechanism in the thermal modification of vegetable oil. Journal of the American Oil Chemists' Society. 89:987-994.
Doll, K.M. 2010. A family tree of methyl oleate-based compounds [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting & Expo. p. 112.
Doll, K.M., Sharma, B.K., Pereira, M.S., Santos, G.F., Suarez, P.A., Erhan, S.Z. 2012. Production of phosphorous-containing oleochemicals through an epoxide route. International Journal of Sustainable Engineering. 5:280-285.
Tisserat, B., Harry O Kuru, R.E., Cermak, S.C., Evangelista, R.L., Doll, K.M. 2012. Potential uses for cuphea oil processing byproducts and processed oils. Industrial Crops and Products. 35:111-120.
Hughes, S.R., Moser, B.R., Harmsen, A.J., Bischoff, K.M., Jones, M.A., Pinkleman, R., Bang, S.S., Doll, K.M., Tasaki, K., Qureshi, N., Liu, S., Saha, B.C., Jackson, Jr, J.S., Cotta, M.A., Rich, J.O., Caimi, P. 2011. High-throughput automated molecular biology platform for production of fuel ethanol yeast capable of expressing high-value heterologous proteins. Proceedings of the Seventh International Starch Technology Conference. p. 21-29.
Doll, K.M., Sharma, B.K. 2012. Physical properties study on partially bio-based lubricant blends: Thermally modified soybean oil with popular commercial esters. International Journal of Sustainable Engineering. 5(1):33-37.
Sharma, B.K., Doll, K.M., Erhan, S.Z. 2011. Modified vegetable oils-based lubricant emulsions [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting. p. 136.
Arca, M., Perez, J.M., Sharma, B.K., Doll, K.M. 2011. Automotive gear oil lubricant from soybean oil [abstract]. Society of Tribologists and Lubrication Engineers Annual Meeting. p. 142.
Doll, K.M., Sharma, B.K., Suarez, P.A. 2011. Synthesis of a phosphorous derivative of Methyl oleate {abstract}. Annual Meeting and Expo of the American Oil Chemists' Society. p. 71.
Liu, Z., Doll, K.M. 2010. Lewis Acid Catalyzed Ring-opening Polymerization of Epoxidized Soybean Oil in Liquid Carbon Dioxide. Proceedings of the 39th United States-Japan Cooperative Program in Natural Resources, Bioenergy and Green Chemistry. p. 8.
Doll, K.M., Sharma, B.K. 2010. Use of Biobased Surfactants to Stabilize Emulsions Relevant for Industrial Lubrication [abstract]. Annual Meeting and Expo of the American Oil Chemists' Society. p. 30.
Hughes, S.R., Moser, B.R., Harmsen, A.J., Robinson, S., Bischoff, K.M., Jones, M.A., Pinkelman, R., Bang, S.B., Tasaki, K., Doll, K.M., Qureshi, N., Liu, S., Saha, B.C., Jackson Jr, J.S., Cotta, M.A., Rich, J.O., Caimi, P. 2010. Production of truncated Candida antarctica Lipase B gene using automated PCR gene assembly protocol and expression in yeast for use in ethanol and biodiesel production [abstract]. Advanced Biofuels Leadership Conference. Talk 3. p. 5.
Doll, K.M., Erhan, S.Z. 2011. Evaluation of a sugar based edible adhesive utilizing a tensile strength tester. Journal of the Association for Laboratory Automation. 16(2):153-156.
Doll, K.M., Sharma, B. 2011. Emulsification of chemically modified vegetable oils for lubricant use. Journal of Surfactants and Detergents. 14:131-138.
Hughes, S.R., Moser, B.R., Harmsen, A.J., Bischoff, K.M., Jones, M.A., Pinkelman, R., Bang, S.S., Tasaki, K., Doll, K.M., Qureshi, N., Liu, S., Saha, B.C., Jackson Jr, J.S., Cotta, M.A., Rich, J.O., Caimi, P. 2010. Production of Candida antaractica Lipase B gene open reading frame using automated PCR gene assembly protocol on robotic workcell and expression in ethanologenic yeast for use as resin-bound biocatalyst in biodiesel production. Journal of the Association for Laboratory Automation. 16(1):17-37. DOI: 10.1016/j.jala.2010.04.002.
Doll, K.M., Sharma, B.K. 2011. Surfactant effects on bio-based emulsions used as lubrication fluids. In: Biresaw, G., Mittal, K.L., editors. Surfactants in Tribology. Vol 2. Boca Raton, FL: Taylor & Francis. p. 173-190.
Sharma, B.K., Doll, K.M., Erhan, S.Z. 2011. Chemically modified fatty acid methyl esters: their potential for use as lubrication fluids and surfactants. In: Biresaw, G., Mittal, K.L., editors. Surfactants in Tribology. Vol 2. Boca Raton, FL: Taylor & Francis. p. 387-408.
Chintareddy, V.R., Oshel, R.E., Doll, K.M., Verkade, J.G. 2010. Potential Large-Scale Production of Conjugated Soybean Oil Catalyzed by Photolyzed Iodine in Hexanes [abstract]. American Chemical Society National Meeting. p. 142.
Doll, K.M. 2009. New Method to Produce an Industrial Lubrication Fluid from Vegetable Oil-based Materials [abstract]. Midwest Cleantech Innovation Competition. p. 1.
Doll, K.M. 2010. Use of NMR Imaging to Determine the Diffusion Coefficient of Water in Bio-based Hydrogels [abstract]. Annual Meeting and Expo of the American Oil Chemists' Society. p. 9.
Hughes, S.R., Rich, J.O., Moser, B.R., Doll, K.M., Bischoff, K.M., Qureshi, N., Jones, M., Tasaki, K. 2009. Production of the anaerobic GMAX-L yeast using high-throughput mating and transformation of Saccharomyces cerevisiae with identified genes For simultaneous cellulosic ethanol and biodiesel production [abstract]. Bradley Biology Chemisty Seminar Series.
Biswas, A., Sharma, B.K., Doll, K.M., Willett, J.L., Erhan, S.Z., Vermillion, K., Cheng, H. 2009. Synthesis of an amine-oleate derivative using an ionic catalyst. Journal of Agricultural and Food Chemistry. 57(1):8136-8141.
Liu, Z., Doll, K.M., Holser, R.A. 2009. Boron Trifluoride Catalized Ring-Opening Polymerization of Epoxidized Soybean Oil in Liquid Carbon Dioxide. Green Chemistry. 11:1774-1789.
Shogren, R.L., Doll, K.M., Willett, J.L., Swift, G. 2009. Solvent-Free Polymerization of L-Aspartic Acid in the Presence of D-Sorbitol to Obtain Water Soluble or Network Copolymers. Polymers and the Environment. 17(1):103-108.
Hughes, S.R., Moser, B.R., Doll, K.M., Tasaki, K., Harmsen, A., Jones, M., Bang, S., Gibbons, W., Butt, T. 2009. GMAX-L Saccharomyces cerevisiae strains for profitable sustainable cellulosic ethanol and biodiesel production concurrently using engineered workcell [abstract]. Center for Process Analytical Chemisty. Abstract No. 2. p. 1.
Hughes, S.R., Tasaki, K., Moser, B., Doll, K., Butt, T., Sterner, D., Bischoff, K., Hector, R., Jones, M., and Bang, S. 2009. GMAX yeast background strain made from industrial tolerant Saccharomyces cerevisiae engineered to convert pretreated Lignocellulosic starch and cellulosic sugars universally to ethanol anaerobically [abstract]. Cambridge Healthtech Institute, Advanced Biofuels Development Summit. Abstract No. 2. p. 3.
Sharma, B.K., Doll, K.M., Perez, J.M., Erhan, S.Z. 2010. Lubricant Properties of Modified Vegetable Oils [abstract]. Society of Tribologists and Lubrication Engineers 64th Annual Meeting. p. 24.
Sharma, B.K., Biswas, A., Doll, K.M., Erhan, S.Z. 2009. Nitrogen Derivatives of Soybean Oil and Fatty Acid Methyl Esters [abstract]. American Oil Chemists' Society. p. 86.
Doll, K.M., Sharma, B.K., Moser, B.R., Erhan, S.Z. 2009. Surface Tension Measurements of Chemically Modified Oleochemical [abstract]. American Oil Chemists' Society. p. 86.
Hughes, S.R., Tasaki, K., Doll, K.M., Moser, B.R., Rich, J.O., Qureshi, N., Hector, R.E., Dien, B.S., Cotta, M.A., Bischoff, K.M., Liu, S., Bang, S., Jones, M. 2009. Automated high throughput GMAX-L strains of Saccharomyces cereviciae for profitable cellulosic ethanol production from industrial hydrosylates [abstract]. Society for In-Vitro Biology. p. 122.
Suarez, P.A., Pereira, M.S., Doll, K.M., Sharma, B.K., Erhan, S.Z. 2009. Epoxidation of Methyl Oleate using Heterogeneous Catalyst. Journal of Industrial and Engineering Chemical Research. 48:3268-3270.
Doll, K.M. 2009. A Convenient Low-Resolution NMR Method for the Determination of the Molecular Weight of Soybean Oil-Based Polymers. Journal of the Association for Laboratory Automation. 14(4):185-189.
Hughes, S.R., Doll, K., Moser, B., Bang, S., Rich, J., Qureshi, N., Hector, R., Dien, B., Cotta, M., Bischoff, K., Liu, S., Jones, M. 2009. Automated production GMAX-L strains of Saccharomyces cereviciae for profitable sustainable cellulosic ethanol production combined with valuable coproduct isolation in mixed biorefinery settings [abstract]. LabAutomation 2009. Abstract No. 109. p. 42.
Erhan, S.Z., Sharma, B.K., Doll, K.M. 2009. Opportunities for Industrial Uses of Agricultural Products. Chemistry Today/Chimica Oggi. 27(1):38-41.
Erhan, S.Z., Sharma, B.K., Doll, K.M. 2009. Production of Agricultural Commodities in the United States. Chemistry Today/Chimica Oggi. 27(1):34-36.
Doll, K.M., Erhan, S.Z. 2008. Emerging Technologies for Development of Green Industrial Products from Natural Oils [abstract]. Malaysian Oil Science and Technology. 17(2):74-79.
Doll, K.M., Erhan, S.Z. 2009. Polyol and Amino Acid-Based Biosurfactants, Builders, and Hydrogels. In: Hayes, D.G., Kitamomo, D., Solaiman, D.K.Y., Ashby, R.D., editors. Biobased Surfactants and Detergents: Synthesis, Properties, and Applications. Urbana, IL: AOCS Press. p. 425-448.
Doll, K.M., Sharma, B.K., Erhan, S.Z. 2008. Lubrication fluids from branched fatty acid methyl esters [abstract]. Midwest Bioenergy Research Forum. Poster 6.
Doll, K.M., Sharma, B.K., Erhan, S.Z. 2008. Synthesis of lubrication fluids and surfactant precursors from soybean oil [abstract]. United States-Japan Cooperative Program in Natural Resources. p. 124-125.
Shogren, R.L., Willett, J.L., Westmoreland, D., Gonzalez, S., Doll, K.M., Swift, G. 2008. Properties of Copolymers of Aspartic Acid and Aliphatic Dicarboxylic Acids Prepared by Reactive Extrusion. Journal of Applied Polymer Science. 110:3348-3354.
Doll, K.M., Sharma, B.K., Erhan, S.Z. 2008. Friction reducing properties and stability of epoxidized oleochemicals. Clean. 36(8):700-705.
Doll, K.M., Moser, B.R., Erhan, S.Z. 2008. Surface Tension Measurements on Oleochemicals Derived from Soybean Oil [abstract}. Industrial Application of Renewable Resources 2008 Program Book. p. 16.
Doll, K.M., Erhan, S.Z. 2008. Synthesis of cyclic acetals (ketals) from oleochemicals using a solvent free method. Green Chemistry. 10(6):712-717.
Tasaki, K., Moser, B.R., Doll, K.M., Hughes, S.R. 2008. Biodiesel production using heterogenous catalyst [abstract]. International Biofuels Development Summit. p. 2.
Doll, K.M., Sharma, B.K., Suarez, P.A., Erhan, S.Z. 2008. Comparing biofuels obtained from pyrolysis, of soybean oil or soapstock, with traditional soybean biodiesel: density, kinematic viscosity, and surface tensions. Energy and Fuels. 22(3):2061-2066.
Doll, K.M., Erhan, S.Z. 2008. Oleochemical synthesis of an acid cleavable hydrophobe for surfactant use [abstract]. American Oil Chemists' Society. p. 147-148.
Erhan, S.Z., Sharma, B.K., Doll, K.M. 2008. Lubricant properties of ester hydroxy derivatives of methyl oleate [abstract]. American Oil Chemists' Society. p. 88.
Suarez, P.A., Costa, M.S., Sharma, B.K., Doll, K.M., Erhan, S.Z. 2008. Epoxidation of methyl oleate using heterogeneous catalyst [abstract]. Chemical Reaction Engineering. p.19.
Erhan, S.Z., Sharma, B.K., Doll, K.M. 2008. Oxidation, Low Temperature, and Lubricating Properties of Chemically-modified Methyl Oleates [abstract]. Lubmat Conference & Exhibition. p. 2.
Erhan, S.Z., Sharma, B.K., Doll, K.M. 2008. Chemically Modified Fatty Acid Methyl Esters: Potential as Lubricant and Surfactant [abstract]. International Symposium on Surfactants in Solution. p. 2.
Sharma, B.K., Doll, K.M., Erhan, S.Z. 2008. Ester hydroxy derivatives of methyl oleate: tribological, oxidation and low temperature properties. Bioresource Technology. 99(15):7333-7340.
Doll, K.M., Kenar, J.A., Erhan, S.Z. 2008. Carbonates from oleochemicals: Biobased materials to value added green chemicals. Chemistry Today/Chimica Oggi. 25(6):7-10.
Doll, K.M., Moser, B.R., Erhan, S.Z. 2007. Surface tension studies of alkyl esters and epoxidized alkyl esters relevant to oleochemically based fuel additives. Energy and Fuels. 21:3044-3048.
Sharma, B.K., Doll, K.M., Erhan, S.Z. 2008. Biobased greases: soap structure and composition effects on tribological properties. In: Biresaw, G., Mittal, K.L., editors. Surfactants in Tribology. Boca Raton, FL: CRC Press. p. 309-323.
Doll, K.M., Sharma, B.K., Erhan, S.Z. 2007. Stability and friction reducing properties of epoxidized oleochemical methyl esters [abstract]. American Chemical Society. p. 16.
Moser, B.R., Sharma, B.K., Doll, K.M., Erhan, S.Z. 2007. Diesters from oleic acid: synthesis, low temperature properties, and oxidation stability. Journal of the American Oil Chemists' Society. 84:675-680.
Kurth, T.L., Sharma, B.K., Doll, K.M., Erhan, S.Z. 2007. Adsorption behavior of epoxidized fatty esters via boundary lubrication coefficient of friction measurements. Chemical Engineering Communications. 194:1065-1077.
Sharma, B.K., Doll, K.M., Erhan, S.Z. 2007. Oxidation, friction reducing, and low temperature properties of epoxy fatty acid methyl esters. Green Chemistry. 9:469-474.
Doll, K.M., Sharma, B.K., Erhan, S.Z. 2007. Synthesis of branched methyl hydroxy stearates including an ester from bio-based levulinic acid. Industrial and Engineering Chemistry Research. 46:3513-3519.
Doll, K.M., Erhan, S.Z. 2007. Oleochemical synthesis of an acid cleavable hydrophobe for surfactant use [abstract]. Annual Meeting and Expo of the American Oil Chemists' Society. p. 97.
Doll, K.M., Moser, B.R., Sharma, B.K., Erhan, S.Z. 2007. Current uses of vegetable oil in the surfactant, fuel, and lubrication industries. Chemistry Today/Chimica Oggi. 24(6):41-44.
Doll, K.M., Erhan, S.Z. 2006. Synthesis and performance of surfactants based on epoxidized methyl oleate and glycerol. Journal of Surfactants and Detergents. 9:377-383.
Doll, K.M., Shogren, R.L., Willett, J.L., Swift, G. 2006. Solvent free polymerization of citric acid and D-sorbitol. Journal of Polymer Science A. 44:4259-4267.
Shogren, R.L., Doll, K.M., Gonzalez, S.O., Willett, J.L., Swift, G. 2006. Preparation and properties of sorbitol citrate polyesters [abstract]. BioEnvironmental Polymer Society Meeting. p.93.
Doll, K.M., Erhan, S.Z. 2006. Synthesis of cyclic carbonates from fatty materials using supercritical carbon dioxide [abstract]. 10th Annual Green Chemistry and Engineering Conference, Designing for a Sustainable Future. p. 24.
Doll, K.M., Erhan, S.Z. 2006. Synthesis of carbonated methyl oleate from methyl oleate epoxide (EMO) in supercritical carbon dioxide [abstract]. 97th American Oil Chemists' Society Annual Meeting and Expo. p. 89.
Doll, K.M., Holser, R.A., Erhan, S.Z. 2006. Surface tension studies of chemically modified oleochemical glycerides. 97th American Oil Chemists' Society Annual Meeting and Expo. p. 72-73.
Doll, K.M., Erhan, S.Z. 2005. The improved synthesis of carbonated soybean oil using supercritical carbon dioxide at a reduced reaction time. Green Chemistry. 7:849-854.
Doll, K.M., Erhan, S.Z. 2005. Synthesis of carbonated fatty methyl esters using supercritical carbon dioxide. Journal of Agricultural and Food Chemistry. 53(24):9608-9614.
Doll, K.M., Shogren, R.L., Holser, R.A., Willett, J.L., Swift, G. 2005. Polymerization of L-aspartic acid to polysuccinimide and copoly(succinimide-aspartate) in supercritical carbon dioxide. Letters in Organic Chemistry. 2:687-689.
Holser, R.A., Doll, K.M., Erhan, S.Z. 2006. Metathesis of vegetable oil esters for improved fuel properties. Fuel. 85(3):393-395.
Doll, K.M., Erhan, S.Z. 2005. Improved synthesis of carbonated soybean oil in supercritical carbon dioxide. American Chemical Society National Meeting. p. 191.
Holser, R.A., Doll, K.M., Erhan, S.Z. 2005. Metathesis of methyl soyate with ruthenium catalysts [abstract]. Annual Meeting and Expo of the American Oil Chemists' Society. p. 56.
Doll, K.M., Erhan, S.Z. 2005. The improved synthesis of carbonated soybean oil in supercritical carbon dioxide. American Chemical Society Abstracts. p.74.
Holser, R.A., Doll, K.M., Erhan, S.Z. 2004. Ionic and non-ionic surfactants prepared from glycerol. Meeting Abstract.
Doll, K.M., Shogren, R.L., Swift, G.G., Willett, J.L. 2004. The synthesis of polysuccinimide and copoly(succinimide-aspartate) in a supercritical fluid [abstract]. 36th Annual Great Lakes Regional American Chemical Society Symposium. p. 175.
Dr. Doll received a B.S. in chemistry in 1995 from the University of Wyoming. His undergraduate research included the synthesis of compounds that were used to detect oxygen in groundwater monitoring sensors. Dr. Doll received a Ph.D. from Colorado State University in 2003, where his research in Vitamin B12 uncovered previously hidden quantum mechanical effects in enzyme activation. The year 2003 was also the year that Dr. Doll joined the USDA at NCAUR in Peoria, Illinois. Dr. Doll was part of the Plant Polymer research unit, where he introduced technology that enabled natural carboxylic acids, including aspartic acid and citric acid, to be incorporated into high performance carbohydrate polymers. Later, Ken moved into oil research, and was able to chemically modify oils into functional lubricant additives that were effective in both bio-based, and petroleum-based, lubricants. Within the Bio-Oils research unit, Dr. Doll led a project that starts with vegetable oils and transforms them into the polymer building blocks for industrial applications and consumer products and may lead to a truly sustainable bio-based aviation fuel. Overall, Dr. Doll's academic record includes over 100 papers, patents, and chapters, and the authorship of 80 scientific presentations.
During his time at the USDA, Dr. Doll has been active in the technology transfer aspects of science. Dr. Doll has worked on multiple research agreements, both as the investigator, and as the actual hands-on worker. Most notably, Dr. Doll has served as a grant reviewer for multiple US science programs and as an auditor for USDA-OIRP and US Department of Defense projects. Dr. Doll was also a member of the ARS patent committee for many years.