Author
MORRIS, KELLY - University Of Georgia | |
LI, XIAO - Auburn University | |
LANGSTON, DAVID - Virginia Tech | |
Davis, Richard | |
Timper, Patricia - Patty | |
GREY, TIMOTHY - University Of Georgia |
Submitted to: Pest Management Science
Publication Type: Peer Reviewed Journal Publication Acceptance Date: 9/4/2017 Publication Date: 10/18/2017 Citation: Morris, K.A., Langston, D.B., Davis, R.F., Timper, P., Li, X., Grey, T.L. 2017. Fluensulfone sorption and mobility as affected by soil type. Pest Management Science. 74:430-437. https://doi.org/10.1002/ps.4724. DOI: https://doi.org/10.1002/ps.4724 Interpretive Summary: Fluensulfone is a chemical that kills multiple types of plant-parasitic nematodes, and it is in a different chemical class from other nematicides. The binding to (adsorption) and release from (desorption) soil as well as the mobility of fluensulfone was evaluated on multiple soils from the United States in laboratory and column experiments. Soil adsorption of fluensulfone increased as organic matter or clay increased but decreased as sand content increased. Fluensulfone soil desorption increased as pH and cation exchange capacity increased. The amount of fluensulfone desorption from various soil types ranged from 26% to 70%. In mobility experiments on Arredondo sand, fluensulfone in water leaching from the soil columns peaked at 3 hours, gradually declining and becoming undetectable after 9 hours. Recovery from water leached from the columns was 45% of the initial fluensulfone applied to the soil surface. In separate experiments, 30 cm long soil columns were saturated with 1 L of water, and then segregated into three-10 cm sections. Fluensulfone recovery was 41, 34, 29, and 13% in Chualar sandy loam, Arredondo sand, Greenville sandy clay loam, and Tifton loamy sand, respectively in the top 10 cm section. We conclude that soil organic matter and clay contents will affect sorption, mobility, and dissipation of fluensulfone. Technical Abstract: Fluensulfone is a fluoroalkenyl chemistry with activity against multiple types of plant-parasitic nematodes. The adsorption, desorption, and mobility of fluensulfone was evaluated on multiple soils from the United States in laboratory and column experiments. Adsorption data regressed to the logarithmic Freundlich equation resulted in isotherm values of 1.24 to 3.28. Soil adsorption of fluensulfone positively correlated with organic matter (0.67) and clay (0.34), but negatively with sand (-0.54). Fluensulfone soil desorption correlated to pH (0.38) and cation exchange capacity (0.44). Fluensulfone desorption from Arredondo sand soil was 26%, other soils ranged from 43 to 70%. In mobility experiments, fluensulfone in the leachate peaked at 3 hours, gradually declining and becoming undetectable after 9 hours. Recovery from leachate was 45% of the initial fluensulfone applied to the soil surface. In separate experiments, 30 cm long soil columns were saturated with 1 L of water, and then segregated into three-10 cm sections. Fluensulfone recovery was 41, 34, 29, and 13% in Chualar sandy loam, Arredondo sand, Greenville sandy clay loam, and Tifton loamy sand, respectively in the top 10 cm section. We conclude that soil organic matter and clay contents will affect sorption, mobility, and dissipation of fluensulfone. |