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ARS Home » Southeast Area » Booneville, Arkansas » Dale Bumpers Small Farms Research Center » Research » Publications at this Location » Publication #351837

Title: Geostatistical mapping of metal elements distribution across conterminous USA

Author
item ADHIKARI, KABINDRA - University Of Arkansas
item Owens, Phillip
item WEST, LARRY - Retired Non ARS Employee
item Ashworth, Amanda
item WILSON, MICHAEL - Retired Non ARS Employee
item MILLER, DAVID - University Of Arkansas

Submitted to: Meeting Abstract
Publication Type: Abstract Only
Publication Acceptance Date: 5/2/2018
Publication Date: N/A
Citation: N/A

Interpretive Summary:

Technical Abstract: Presence of metal elements in soils and in the environment in toxic levels pose potential health hazards. Assessment and proper management of sites contaminated with toxic metals requires a precise information on the spatial distribution of these metals. This study aims to model and map the spatial distribution of Cd, Cu, Ni, Pb and Zn across conterminous USA using point observations and geostatistics. About 4,400 surface soil observations on Cd, Cu, Ni, Pb and Zn concentrations were compiled from the USDA-NRCS databases to use in this study. Spatial autocorrelation of these elements was quantified with a variogram, and the continuous maps were generated using ordinary kriging. Prediction uncertainty was assessed through prediction standard error map and by cross-validation. Average Cd and Zn in the study area were 0.37 mg.kg-1 and 68.6 mg.kg-1, respectively; whereas, average Cu, Ni, and Pb ranged between 29 to 31 mg kg-1. A stable variogram was found to be the best model to quantify spatial autocorrelation of the elements. Based on cross-validation, Cd has the highest prediction performance and Ni had the lowest. In general, the southeastern parts of the USA had lower concentrations of most toxic elements compared to the rest of the USA. Cu was found higher along the north eastern and west coast; whereas, a toxic concentration of Pb was predicted towards the northeast and a small area in the west north. The results presented in this study provide general trends based on the available data. Nevertheless, results from this study give some general information on the spatial behaviours and general distribution pattern of toxic metal elements across conterminous USA. In the future, mapping with some advanced digital techniques will be adopted in which several soil-environmental variables can be used as predictors of these toxic metals and will be included.